Benchmarks for multicomponent reactive transport across a cement/clay interface     

Nicolas C. M. Marty  Olivier Bildstein  Philippe Blanc  Francis Claret  Benoit Cochepin  Eric C. Gaucher  Diederik Jacques  Jean-Eric Lartigue  Sanheng Liu  K. Ulrich Mayer  Johannes C. L. Meeussen  Isabelle Munier  Ingmar Pointeau  Danyang Su  Carl I. Steefel 《Computational Geosciences》2015,19(3):635-653

  相似文献   

Can shallow open-loop hydrothermal well-doublets help remediate seawater intrusion?     

François De Keuleneer  Philippe Renard 《Hydrogeology Journal》2015,23(4):619-629

  相似文献   

Highly gravity-driven flow of a NAPL in water-saturated porous media using the discontinuous Galerkin finite-element method with a generalised Godunov scheme     

Lauriane Schneider  Raphaël di Chiara Roupert  Gerhard Schäfer  Philippe Helluy 《Computational Geosciences》2015,19(4):855-876

  相似文献   

Laura Sigg: Investigating the Speciation,Bioavailability and Ecotoxicology of Trace Metals in Natural Waters     

Bernhard Wehrli  Philippe Behra 《Aquatic Geochemistry》2015,21(2-4):59-64

  相似文献   

Prediction-Focused Subsurface Modeling: Investigating the Need for Accuracy in Flow-Based Inverse Modeling   总被引：1，自引：1，他引：0  

Céline Scheidt  Philippe Renard  Jef Caers 《Mathematical Geosciences》2015,47(2):173-191

  相似文献   

Fluid migration at the basement/sediment interface along the margin of the Southeast basin (France): implications for Pb–Zn ore formation     

Luc Aquilina  Philippe Boulvais  Jean-Rémi Mossmann 《Mineralium Deposita》2011,46(8):959-979

This study investigates the isotopic composition (C, O, S and Sr) of carbonates, sulphates and sulphide cements in the rock matrix and fracture fillings in geological formations of the Southeast basin of France, using core samples collected during the Deep Geology of France programme (GPF Ardèche theme). The Southeast basin belongs to the Alpine Tethyan margin. It is one of the thickest sedimentary basins in Europe, reaching upwards of 9 km in certain locations. The main fluid transfer from the basin is related to the large Pb–Zn Mississippi Valley-type district along the southern margin of the Massif Central block. A synthesis of the tectonic, mineralogical and petrographic investigations on the GPF boreholes shows that a major fluid circulation event occurred across the Alpine margin of Tethys during the Early Jurassic (Hettangian–Bathonian). It produced a general cementation of the rock porosity through precipitation of dolomite, sulphate and barite. Fracture fillings yield isotopic signatures distinct from the matrix cements. Matrix cements have particular characteristics, i.e. δ³⁴S and δ¹³C that agree with a marine origin. The δ³⁴S values of Permo-Carboniferous to Triassic sulphides from fracture cements are interpreted as resulting from the thermo-chemical reduction of sulphates. Fracture sulphates in the same geological formations yield δ³⁴S values that define a relatively homogeneous end-member, whose composition is similar to sulphates in the Largentière Pb–Zn ore deposit. The source of S is attributed to the Permo-Carboniferous succession. The borehole fracture fillings are attributed to a major fluid circulation stage compatible with the Early Jurassic stage identified from the geological investigation of the boreholes. The formation of the Largentière deposit is considered as resulting from the mixing of this Early Jurassic fluid with continental hydrothermal fluids circulating in a basement horst, along its margin with the sedimentary basin. Other Pb–Zn deposits may also be related to fluid migration along the basement/sedimentary cover interface in the eastern and western parts of the Massif Central. This regional fluid circulation event may represent a geodynamic marker of the Jurassic extensional phase.  相似文献   

Degradation of natural organic matter: A thermodynamic analysis     

Douglas E. LaRowe  Philippe Van Cappellen 《Geochimica et cosmochimica acta》2011,75(8):2030-16486

  相似文献   

Contrasting isotopic signatures between anthropogenic and geogenic Zn and evidence for post-depositional fractionation processes in smelter-impacted soils from Northern France   总被引：2，自引：0，他引：2  

Farid Juillot  Delphine Jouvin  Philipe Telouk  Philippe Ildefonse  Steve Sutton  Gordon E. Brown Jr. 《Geochimica et cosmochimica acta》2011,75(9):2295-2308

Zinc isotopes have been studied along two smelter-impacted soil profiles sampled near one of the largest Pb and Zn processing plants in Europe located in northern France, about 50 km south of Lille. Mean δ⁶⁶Zn values along these two soil profiles range from +0.22 ± 0.17‰ (2σ) to +0.34 ± 0.17‰ (2σ) at the lowest horizons and from +0.38 ± 0.45‰ (2σ) to +0.76 ± 0.14‰ (2σ) near the surface. The δ⁶⁶Zn values in the lowest horizons of the soils are interpreted as being representative of the local geochemical background (mean value +0.31 ± 0.38‰), whereas heavier δ⁶⁶Zn values near the surface of the two soils are related to anthropogenic Zn. This anthropogenic Zn occurs in the form of franklinite (ZnFe₂O₄)-bearing slag grains originating from processing wastes at the smelter site and exhibiting δ⁶⁶Zn values of +0.81 ± 0.20‰ (2σ). The presence of franklinite is indicated by EXAFS analysis of the topsoil samples from both soil profiles as well as by micro-XANES analysis of the surface horizon of a third smelter-impacted soil from a distant site. These results indicate that naturally occurring Zn and smelter-derived Zn exhibit significantly different δ⁶⁶Zn values, which suggests that zinc isotopes can be used to distinguish between geogenic and anthropogenic sources of Zn in smelter-impacted soils. In addition to a possible influence of additional past sources of light Zn (likely Zn-sulfides and Zn-sulfates directly emitted by the smelter), the light δ⁶⁶Zn values in the surface horizons compared to smelter-derived slag materials are interpreted as resulting mainly from fractionation processes associated with biotic and/or abiotic pedological processes (Zn-bearing mineral precipitation, Zn complexation by organic matter, and plant uptake of Zn). This conclusion emphasizes the need for additional Zn isotopic studies before being able to use Zn isotopes to trace sources and pathways of this element in surface environments.  相似文献   

Identification of Groundwater Parameters Using an Adaptative Multiscale Method     

Samer Majdalani  Philippe Ackerer 《Ground water》2011,49(4):548-559

The identification of groundwater parameters in heterogeneous systems is a major challenge in groundwater modeling. Flexible parameterization methods are needed to assess the complexity of the spatial distributions of these parameters in real aquifers. In this article, we introduce an adaptative parameterization to identify the distribution of hydraulic conductivity within the large‐scale (4400 km²) Upper Rhine aquifer. The method is based on adaptative multiscale triangulation (AMT) coupled with an inverse problem procedure that identifies the parameters' distributions by reducing the error between measured and simulated heads. The AMT method has the advantage of combining both zonation and interpolation approaches. The AMT method uses area‐based interpolation rather than an interpolation based on stochastic features. The method is applied to a standard 2D groundwater model that takes into account the interactions between the aquifer and surface water bodies, groundwater recharge, and pumping wells. The simulation period covers 204 months, from January 1986 to December 2002. Recordings at 109 piezometers are used for model calibration. The simulated heads are globally quite accurate and reproduce the main dynamics of the system. The local hydraulic conductivities resulting from the AMT method agree qualitatively with existing local experimental observations across the Rhine aquifer.  相似文献   

Effects of seawater acidification on early development of the intertidal sea urchin Paracentrotus lividus (Lamarck 1816)     

Laure Moulin  Ana Isabel Catarino  Thomas Claessens  Philippe Dubois 《Marine pollution bulletin》2011,62(1):48-54

The effect of pH ranging from 8.0 to 6.8 (total scale - pH_T) on fertilization, cleavage and larval development until pluteus stage was assessed in an intertidal temperate sea urchin. Gametes were obtained from adults collected in two contrasting tide pools, one showing a significant nocturnal pH decrease (lowest pH_T = 7.4) and another where pH was more stable (lowest pH_T = 7.8). The highest pH_T at which significant effects on fertilization and cleavage were recorded was 7.6. On the contrary, larval development was only affected below pH_T 7.4, a value equal or lower than that reported for several subtidal species. This suggests that sea urchins inhabiting stressful intertidal environments produce offspring that may better resist future ocean acidification. Moreover, at pH_T 7.4, the fertilization rate of gametes whose progenitors came from the tide pool with higher pH decrease was significantly higher, indicating a possible acclimatization or adaptation of gametes to pH stress.  相似文献